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Accueil du site > Production scientifique > Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

Date de publication: 29 mai 2015

M. Katari, E. Oayen de la Garanderie, E. Nicol, V. Steinmetz, G. van der Rest, D. Carmicahel, G. Frison
Phys. Chem. Chem. Phys. 17 25689-25692 (2015). DOI

Travail réalisé sur le site de l’Université Paris Sud.

Abstract

Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono–ligated complex has been demonstrated.