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Accueil du site > Production scientifique > Self-assembled containers based on extended tetrathiafulvalene.

Self-assembled containers based on extended tetrathiafulvalene.

Date de publication: 24 juin 2013

Bivaud S, Goeb S, Croué V, Dron PI, Allain M, Sallé M.
J. Am. Chem. Soc. 17 10018-21 (2013). DOI

Travail réalisé sur le site de l’Université de Lorraine.

Abstract

Two original self-assembled containers constituted each by six electroactive subunits are described. They are synthesized from a concave tetratopic π-extended tetrathiafulvalene ligand bearing four pyridyl units and cis-M(dppf)(OTf)2 (M = Pd or Pt ; dppf = 1,1’-bis(diphenylphosphino)ferrocene ; OTf = trifluoromethane-sulfonate) complexes. Both fully characterized assemblies present an oblate spheroidal cavity that can incorporate one perylene molecule.